Two synthetic routes have been defined for the preparation of a 5,10,15-triferrocenylcorrole Cu derivative. This complex has been characterized and the preliminary electrochemical investigation shows a strong interaction among the corrole and meso ferrocenyl substituents. The results obtained suggest that peculiar properties are gained by combining the eccentric characteristics of ferrocenyl substitution with the corrole macrocycle.
Pomarico, G., Vecchi, A., Mandoj, F., Bortolini, O., Cicero, D.o., Galloni, P., et al. (2014). The corrole and ferrocene marriage: 5,10,15-triferrocenylcorrolato Cu. CHEMICAL COMMUNICATIONS, 50(31), 4076-4078 [10.1039/c3cc49416k].
The corrole and ferrocene marriage: 5,10,15-triferrocenylcorrolato Cu
MANDOJ, FEDERICA;CICERO, DANIEL OSCAR;GALLONI, PIERLUCA;PAOLESSE, ROBERTO
2014-01-01
Abstract
Two synthetic routes have been defined for the preparation of a 5,10,15-triferrocenylcorrole Cu derivative. This complex has been characterized and the preliminary electrochemical investigation shows a strong interaction among the corrole and meso ferrocenyl substituents. The results obtained suggest that peculiar properties are gained by combining the eccentric characteristics of ferrocenyl substitution with the corrole macrocycle.| File | Dimensione | Formato | |
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ChemComm 2014 p4076(CuTFcC).pdf
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