Two synthetic routes have been defined for the preparation of a 5,10,15-triferrocenylcorrole Cu derivative. This complex has been characterized and the preliminary electrochemical investigation shows a strong interaction among the corrole and meso ferrocenyl substituents. The results obtained suggest that peculiar properties are gained by combining the eccentric characteristics of ferrocenyl substitution with the corrole macrocycle.

Pomarico, G., Vecchi, A., Mandoj, F., Bortolini, O., Cicero, D.o., Galloni, P., et al. (2014). The corrole and ferrocene marriage: 5,10,15-triferrocenylcorrolato Cu. CHEMICAL COMMUNICATIONS, 50(31), 4076-4078 [10.1039/c3cc49416k].

The corrole and ferrocene marriage: 5,10,15-triferrocenylcorrolato Cu

MANDOJ, FEDERICA;CICERO, DANIEL OSCAR;GALLONI, PIERLUCA;PAOLESSE, ROBERTO
2014

Abstract

Two synthetic routes have been defined for the preparation of a 5,10,15-triferrocenylcorrole Cu derivative. This complex has been characterized and the preliminary electrochemical investigation shows a strong interaction among the corrole and meso ferrocenyl substituents. The results obtained suggest that peculiar properties are gained by combining the eccentric characteristics of ferrocenyl substitution with the corrole macrocycle.
Pubblicato
Rilevanza internazionale
Articolo
Esperti anonimi
Settore CHIM/06 - Chimica Organica
Settore CHIM/07 - Fondamenti Chimici delle Tecnologie
English
Con Impact Factor ISI
PHOTOINDUCED CHARGE-TRANSFER; METAL-FREE; SUBSTITUTED CORROLES; ELECTRONIC-STRUCTURE; PORPHYRINS; RADICALS; DYADS
Pomarico, G., Vecchi, A., Mandoj, F., Bortolini, O., Cicero, D.o., Galloni, P., et al. (2014). The corrole and ferrocene marriage: 5,10,15-triferrocenylcorrolato Cu. CHEMICAL COMMUNICATIONS, 50(31), 4076-4078 [10.1039/c3cc49416k].
Pomarico, G; Vecchi, A; Mandoj, F; Bortolini, O; Cicero, Do; Galloni, P; Paolesse, R
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2108/85349
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