A novel method for the preparation of beta-fused porphyrin dyads was developed that exploits a one-pot reaction of 2,3-diaminoporphyrins with diethyl oxalate. This approach provides good yields of the zinc beta-fused dyad and the corresponding free-base, opening the way for preparation of several metal derivatives to permit modulation of optoelectronic characteristics for commercial applications. (C) 2013 Elsevier Ltd. All rights reserved.
Mandoj, F., Nardis, S., Pudi, R., Lvova, L., Fronczek, F., Smith, K., et al. (2013). beta-Pyrazino-fused tetrarylporphyrins. DYES AND PIGMENTS, 99(1), 136-143 [10.1016/j.dyepig.2013.04.024].
beta-Pyrazino-fused tetrarylporphyrins
MANDOJ, FEDERICA;NARDIS, SARA;Lvova, L;PAOLESSE, ROBERTO
2013-01-01
Abstract
A novel method for the preparation of beta-fused porphyrin dyads was developed that exploits a one-pot reaction of 2,3-diaminoporphyrins with diethyl oxalate. This approach provides good yields of the zinc beta-fused dyad and the corresponding free-base, opening the way for preparation of several metal derivatives to permit modulation of optoelectronic characteristics for commercial applications. (C) 2013 Elsevier Ltd. All rights reserved.File in questo prodotto:
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