5,10,15-Triaryltetrabenzocorrole complexes of aluminum, gallium, germanium, and phosphorus were synthesized by coordination of these metal ions in the preformed triaryltetrabenzocorrole macrocycle, opening a way to the investigation of different metal complexes. The UV−vis spectra of these derivatives exhibit a red shift and broadening of all absorption bands because of the π-extended aromatic system and distortion of the molecular framework. The electrochemical and photophysical behaviors of the free base and the metal complexes of meso-triaryltetrabenzocorrole were investigated and characterized.
Pomarico, G., Nardis, S., Naitana, M., Vicente, M., Kadish, K., Chen, P., et al. (2013). Aluminum, Gallium, Germanium, Copper, and Phosphorus Complexes of meso-Triaryltetrabenzocorrole. INORGANIC CHEMISTRY, 52(7), 4061-4070 [10.1021/ic400162y].
Aluminum, Gallium, Germanium, Copper, and Phosphorus Complexes of meso-Triaryltetrabenzocorrole
NARDIS, SARA;PAOLESSE, ROBERTO
2013-01-01
Abstract
5,10,15-Triaryltetrabenzocorrole complexes of aluminum, gallium, germanium, and phosphorus were synthesized by coordination of these metal ions in the preformed triaryltetrabenzocorrole macrocycle, opening a way to the investigation of different metal complexes. The UV−vis spectra of these derivatives exhibit a red shift and broadening of all absorption bands because of the π-extended aromatic system and distortion of the molecular framework. The electrochemical and photophysical behaviors of the free base and the metal complexes of meso-triaryltetrabenzocorrole were investigated and characterized.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
