The heat is on: A Cu5 metal cluster presents distinctive photophysical properties that result in a temperature-dependent fluorescent quantum yield and excited-state lifetime between −45 and +80 °C, both in solution and as a solid. Unprecedented accuracy in temperature determination by fluorescence measurements was achieved with this complex, thus making it suitable for applications in, for example, biology and (nano)materials research.
Cauzzi, D., Pattacini, R., Delferro, M., Dini, F., DI NATALE, C., Paolesse, R., et al. (2012). Temperature-Dependent Fluorescence of Cu5 Metal Clusters: A Molecular Thermometer. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 51(38), 9662-9665 [10.1002/anie.201204052].
Temperature-Dependent Fluorescence of Cu5 Metal Clusters: A Molecular Thermometer
DI NATALE, CORRADO;PAOLESSE, ROBERTO;
2012-01-01
Abstract
The heat is on: A Cu5 metal cluster presents distinctive photophysical properties that result in a temperature-dependent fluorescent quantum yield and excited-state lifetime between −45 and +80 °C, both in solution and as a solid. Unprecedented accuracy in temperature determination by fluorescence measurements was achieved with this complex, thus making it suitable for applications in, for example, biology and (nano)materials research.| File | Dimensione | Formato | |
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