1′-Acetyl-1-α-hydroxyethyl- and 1,1′-bis(α-hydroxyethyl)ferrocenes and the carbocations derived from them have been characterized by electronic, infrared and NMR spectroscopy. The existence of intramolecular hydrogen bonds between the interannular substituents in the various species examined has been established. The restricted rotation caused by such interaction leads to preferential formation of pairs of enantiomers.

Cerichelli, G., Floris, B., Ortaggi, G. (1974). Stereochemical consequences of the intramolecular hydrogen bond in 1′-acetyl-1-α-hydroxyethyl- and 1,1′-bis(α-hydroxyethyl)ferrocenes. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 76(1), 73-79.

Stereochemical consequences of the intramolecular hydrogen bond in 1′-acetyl-1-α-hydroxyethyl- and 1,1′-bis(α-hydroxyethyl)ferrocenes

FLORIS, BARBARA;
1974-01-01

Abstract

1′-Acetyl-1-α-hydroxyethyl- and 1,1′-bis(α-hydroxyethyl)ferrocenes and the carbocations derived from them have been characterized by electronic, infrared and NMR spectroscopy. The existence of intramolecular hydrogen bonds between the interannular substituents in the various species examined has been established. The restricted rotation caused by such interaction leads to preferential formation of pairs of enantiomers.
1974
Pubblicato
Rilevanza internazionale
Articolo
Esperti anonimi
Settore CHIM/06 - Chimica Organica
English
Cerichelli, G., Floris, B., Ortaggi, G. (1974). Stereochemical consequences of the intramolecular hydrogen bond in 1′-acetyl-1-α-hydroxyethyl- and 1,1′-bis(α-hydroxyethyl)ferrocenes. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 76(1), 73-79.
Cerichelli, G; Floris, B; Ortaggi, G
Articolo su rivista
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2108/64132
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