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EnglishCopper oxycarbonate thin films of the (CaCuO2)(m)(Ba(2-x)A(x)CuO(2)CO(3))(n) (A = Ca, Sr) system have been deposited, using the pulsed laser deposition (PLD) technique, on (100) LaAlO3 and (110) NdGaO3 substrates. The m = 0 member of the family, Ba2-xSrxCuO2CO3 (x = 0.1 and x = 0.4) has been deposited in a selective way for the first time on both LaAlO3 and NdGaO3. The best results have been obtained for NdGaO3 substrates, but a double orientation of the film, [001] and [110], is found by transmission electron microscopy (TEM) for x = 0.4. Ba2-xCaxCuO2CO3 (x = 0.2) has also been studied. At a deposition temperature of 620 degrees C, a Ba2CuO2CO3 (B2CC) type structure is stabilized, whereas at 680 degrees C another perovskite is isolated. Attempts to deposit the member (m = 1, n = 1, x = 0) of the family, i.e., Ba2CaCu2O4CO3, on LaAlO3 using a single multiphase sintered ceramic target led to the formation of a B2CC type structure (m = 0) coherently intergrown with CaCu2O3 and Ca2CuO3 extended defects. The structures and structural mechanisms are discussed. No diamagnetic transition was observed in any of these films down to 5 K.
Prellier W., T.A. (1997). Pulsed laser deposition of Ba(2-x)A(x)CuO(2)CO(3) (A=Ca, Sr) thin films, m=0 member of the series (CaCuO2)(m)(Ba(2-x)A(x)CuO(2)CO(3))(n) (A=Ca, Sr). CHEMISTRY OF MATERIALS, 9(1), 119-126.
| Tipologia: | Articolo su rivista | |
| Citazione: | Prellier W., T.A. (1997). Pulsed laser deposition of Ba(2-x)A(x)CuO(2)CO(3) (A=Ca, Sr) thin films, m=0 member of the series (CaCuO2)(m)(Ba(2-x)A(x)CuO(2)CO(3))(n) (A=Ca, Sr). CHEMISTRY OF MATERIALS, 9(1), 119-126. | |
| Lingua: | English | |
| Settore Scientifico Disciplinare: | Settore FIS/03 - Fisica della Materia | |
| Revisione (peer review): | Sì, ma tipo non specificato | |
| Tipo: | Articolo | |
| Rilevanza: | Rilevanza internazionale | |
| Stato di pubblicazione: | Pubblicato | |
| Data di pubblicazione: | 1997 | |
| Titolo: | Pulsed laser deposition of Ba(2-x)A(x)CuO(2)CO(3) (A=Ca, Sr) thin films, m=0 member of the series (CaCuO2)(m)(Ba(2-x)A(x)CuO(2)CO(3))(n) (A=Ca, Sr) | |
| Autori: | ||
| Autori: | Prellier W., Tebano A., Allen J.L., Hamet J.F., Mercey B., Hervieu M., Raveau B. | |
| Appare nelle tipologie: | 01 - Articolo su rivista |
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