Three phenolic model compounds representing bonding patterns of residual kraft lignin were incubated with manganese peroxidase from Lentinula edodes. Extensive degradation of all the phenolic models, mainly occurring via side-chain benzylic oxidation, was observed. Among the tested model compounds the diphenylmethane alpha-5 phenolic model was found to be the most reactive, yielding several products showing oxidation and fragmentation at the bridging position. The non-phenolic 5-5' biphenyl and 5-5' diphenylmethane models were found unreactive. (C) 2000 Elsevier Science Ltd. All rights reserved.
Crestini C., D.A. (2000). The reactivity of phenolic and non-phenolic residual kraft lignin model compounds with Mn(II)-peroxidase from Lentinula edodes. BIOORGANIC & MEDICINAL CHEMISTRY, 8(2), 433-438.
Tipologia: | Articolo su rivista |
Citazione: | Crestini C., D.A. (2000). The reactivity of phenolic and non-phenolic residual kraft lignin model compounds with Mn(II)-peroxidase from Lentinula edodes. BIOORGANIC & MEDICINAL CHEMISTRY, 8(2), 433-438. |
IF: | Con Impact Factor ISI |
Lingua: | English |
Settore Scientifico Disciplinare: | Settore CHIM/03 - Chimica Generale e Inorganica |
Revisione (peer review): | Sì, ma tipo non specificato |
Tipo: | Articolo |
Rilevanza: | Rilevanza internazionale |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1016/S0968-0896(99)00303-X |
Stato di pubblicazione: | Pubblicato |
Data di pubblicazione: | 2000 |
Titolo: | The reactivity of phenolic and non-phenolic residual kraft lignin model compounds with Mn(II)-peroxidase from Lentinula edodes |
Autori: | |
Autori: | Crestini C., D'Annibale A., Sermanni G.G., Saladino R. |
Appare nelle tipologie: | 01 - Articolo su rivista |