We have performed an extended x-ray-absorption fine-structure (EXAFS) measurement of Cd1-xMnxTe solid solutions for various concentrations x in the single-phase range 0≤x≤0.7. Data have been collected on the Mn K, Cd LIII, and Te LIII edges. We have found well-defined different nearest-neighbor Cd-Te and Mn-Te distances almost independent of x. A model of the microscopic structure of the zinc-blende-type A1-xBxC ternary alloys based on a random distribution of cations has been developed. The model describes the bimodal distribution of near-neighbor distances in terms of distortion of the anion sublattice (the cation sublattice is assumed to remain fixed) with use only of the lattice constants of the alloy and the bond-stretching constants of each binary component. Its application to Cd1-xMnxTe and In1-xGaxAs alloys is proved to be in good agreement with the EXAFS results. Within the framework of this model we also consider the problem of the structural stability of Cd1-xMnxTe.
Balzarotti, A., Notta, N., Kisiel, A., Zimnal Starnawska, M., Czyzyk, M., Podgorny, M. (1985). Model of the local structure of random ternary alloys:Experiment versus theory. PHYSICAL REVIEW. B, CONDENSED MATTER, 31(12), 7526-7539 [10.1103/PhysRevB.31.7526].
Model of the local structure of random ternary alloys:Experiment versus theory
BALZAROTTI, ADALBERTO;
1985-01-01
Abstract
We have performed an extended x-ray-absorption fine-structure (EXAFS) measurement of Cd1-xMnxTe solid solutions for various concentrations x in the single-phase range 0≤x≤0.7. Data have been collected on the Mn K, Cd LIII, and Te LIII edges. We have found well-defined different nearest-neighbor Cd-Te and Mn-Te distances almost independent of x. A model of the microscopic structure of the zinc-blende-type A1-xBxC ternary alloys based on a random distribution of cations has been developed. The model describes the bimodal distribution of near-neighbor distances in terms of distortion of the anion sublattice (the cation sublattice is assumed to remain fixed) with use only of the lattice constants of the alloy and the bond-stretching constants of each binary component. Its application to Cd1-xMnxTe and In1-xGaxAs alloys is proved to be in good agreement with the EXAFS results. Within the framework of this model we also consider the problem of the structural stability of Cd1-xMnxTe.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
