Well-separated diamond particles were nucleated and grown by hot filament chemical vapor deposition (HFCVD) onto WC-Co cemented carbide pretreated by Murakami's reagent and H2O2 + H2SO4 solution. The adhesive strength of diamond particles to WC-Co cemented carbide was quantitatively determined in terms of interface toughness by directly applying an external load to the CVD diamond particles. From the measurement of the maximum load required to scratch off the particles, we determined that the adhesive toughness was 14 J/m(2). This value is more than twice as high as that of CVD diamond on smooth silicon substrate and comparable to the cleavage fracture energy of diamond. The newly developed procedure will allow to check the effectiveness of substrate surface pretreatments for further improving the adhesion level of diamond films on WC-Co. (C) 2000 Elsevier Science S.A. All rights reserved.

Kamiya, S., Takahashi, H., Polini, R., Traversa, E. (2000). Quantitative determination of the adhesive fracture toughness of CVD diamond to WC-Co cemented carbide. DIAMOND AND RELATED MATERIALS, 9(2), 191-194 [10.1016/S0925-9635(00)00229-6].

Quantitative determination of the adhesive fracture toughness of CVD diamond to WC-Co cemented carbide

POLINI, RICCARDO;TRAVERSA, ENRICO
2000-01-01

Abstract

Well-separated diamond particles were nucleated and grown by hot filament chemical vapor deposition (HFCVD) onto WC-Co cemented carbide pretreated by Murakami's reagent and H2O2 + H2SO4 solution. The adhesive strength of diamond particles to WC-Co cemented carbide was quantitatively determined in terms of interface toughness by directly applying an external load to the CVD diamond particles. From the measurement of the maximum load required to scratch off the particles, we determined that the adhesive toughness was 14 J/m(2). This value is more than twice as high as that of CVD diamond on smooth silicon substrate and comparable to the cleavage fracture energy of diamond. The newly developed procedure will allow to check the effectiveness of substrate surface pretreatments for further improving the adhesion level of diamond films on WC-Co. (C) 2000 Elsevier Science S.A. All rights reserved.
2000
Pubblicato
Rilevanza internazionale
Articolo
Sì, ma tipo non specificato
Settore CHIM/03 - CHIMICA GENERALE E INORGANICA
Settore ING-IND/22 - SCIENZA E TECNOLOGIA DEI MATERIALI
English
Con Impact Factor ISI
chemical vapor deposition; diamond film; interface toughness; mechanical properties; adhesion; tungsten carbide
Kamiya, S., Takahashi, H., Polini, R., Traversa, E. (2000). Quantitative determination of the adhesive fracture toughness of CVD diamond to WC-Co cemented carbide. DIAMOND AND RELATED MATERIALS, 9(2), 191-194 [10.1016/S0925-9635(00)00229-6].
Kamiya, S; Takahashi, H; Polini, R; Traversa, E
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2108/44625
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