The first example of deposition of Langmuir-Blodgett (LB) films of a manganese complex of corrole is described. Characterization of the morphological and molecular structure of these LB films has been carried out by means of different microscopic and spectroscopic methods. Depositions onto different substrates afford very uniform films of determined thickness; all the experiments carried out suggest that manganese correlates in LB films are normally oriented to the substrate, with a face-to-face packing of the macrocycles, due to pi-pi interactions. The interactions of these LB films with different volatile organic compounds (VOCs) have been investigated using the quartz microbalance (QMB) technique.

Paolesse, R., DI NATALE, C., Macagnano, A., Sagone, F., Scarselli, M.a., Chiaradia, P., et al. (1999). Langmuir-Blodgett films of a manganese corrole derivative. LANGMUIR, 15(4), 1268-1274 [10.1021/la9712909].

Langmuir-Blodgett films of a manganese corrole derivative

PAOLESSE, ROBERTO;DI NATALE, CORRADO;SCARSELLI, MANUELA ANGELA;CHIARADIA, PIETRO;D'AMICO, ARNALDO
1999

Abstract

The first example of deposition of Langmuir-Blodgett (LB) films of a manganese complex of corrole is described. Characterization of the morphological and molecular structure of these LB films has been carried out by means of different microscopic and spectroscopic methods. Depositions onto different substrates afford very uniform films of determined thickness; all the experiments carried out suggest that manganese correlates in LB films are normally oriented to the substrate, with a face-to-face packing of the macrocycles, due to pi-pi interactions. The interactions of these LB films with different volatile organic compounds (VOCs) have been investigated using the quartz microbalance (QMB) technique.
Pubblicato
Rilevanza internazionale
Articolo
Esperti anonimi
Settore CHIM/07 - Fondamenti Chimici delle Tecnologie
Settore FIS/03 - Fisica della Materia
English
Con Impact Factor ISI
Deposition; Manganese compounds; Molecular orientation; Molecular structure; Morphology; Substrates; Volatile organic compounds; Manganese corrole; Quartz microbalance technique; Langmuir Blodgett films
Paolesse, R., DI NATALE, C., Macagnano, A., Sagone, F., Scarselli, M.a., Chiaradia, P., et al. (1999). Langmuir-Blodgett films of a manganese corrole derivative. LANGMUIR, 15(4), 1268-1274 [10.1021/la9712909].
Paolesse, R; DI NATALE, C; Macagnano, A; Sagone, F; Scarselli, Ma; Chiaradia, P; Troitsky, V; Berzina, T; D'Amico, A
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2108/44547
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