Porphyrinoids are suitable sensitive materials for potentiometric electronic tongues. In this paper, we take advantage of these properties to develop an electronic tongue using an extended-gate field-effect transistor as a signal transducer. The sensitive films were made of different porphyrins and corroles electropolymerized in situ onto laser-induced graphene electrodes. The electronic tongue was duly characterized with respect to ascorbic acid, a common natural antioxidant. The sensors were shown to be sensitive and selective with respect to common interferents, such as dopamine and uric acid. Finally, the sensors were tested to detect ascorbic acid in artificial tears.

Pushparaj, K., DI ZAZZO, L., Allegra, V., Capuano, R., Catini, A., Magna, G., et al. (2025). Detection of ascorbic acid in tears with an extended-gate field-effect transistor-based electronic tongue made of electropolymerized porphyrinoids on laser-induced graphene electrodes. CHEMOSENSORS, 13(3) [10.3390/chemosensors13030108].

Detection of ascorbic acid in tears with an extended-gate field-effect transistor-based electronic tongue made of electropolymerized porphyrinoids on laser-induced graphene electrodes

Kishore Pushparaj;Lorena Di Zazzo;Valerio Allegra;Rosamaria Capuano;Alexandro Catini;Gabriele Magna;Roberto Paolesse;Corrado Di Natale
2025-01-01

Abstract

Porphyrinoids are suitable sensitive materials for potentiometric electronic tongues. In this paper, we take advantage of these properties to develop an electronic tongue using an extended-gate field-effect transistor as a signal transducer. The sensitive films were made of different porphyrins and corroles electropolymerized in situ onto laser-induced graphene electrodes. The electronic tongue was duly characterized with respect to ascorbic acid, a common natural antioxidant. The sensors were shown to be sensitive and selective with respect to common interferents, such as dopamine and uric acid. Finally, the sensors were tested to detect ascorbic acid in artificial tears.
2025
Pubblicato
Rilevanza internazionale
Articolo
Esperti anonimi
Settore CHIM/07
Settore ING-INF/01
Settore CHEM-06/A - Fondamenti chimici delle tecnologie
English
Ascorbic acid; EGFET; Electropolymerization; Human tears; Laser-induced graphene; Porphyrinoids
Pushparaj, K., DI ZAZZO, L., Allegra, V., Capuano, R., Catini, A., Magna, G., et al. (2025). Detection of ascorbic acid in tears with an extended-gate field-effect transistor-based electronic tongue made of electropolymerized porphyrinoids on laser-induced graphene electrodes. CHEMOSENSORS, 13(3) [10.3390/chemosensors13030108].
Pushparaj, K; DI ZAZZO, L; Allegra, V; Capuano, R; Catini, A; Magna, G; Paolesse, R; DI NATALE, C
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2108/419343
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