This study investigates the effect of detonation nanodiamonds (DND) in preserving cellulose dispersions, specifically hydroxyethyl cellulose (HEC) and hydroxypropyl cellulose (HPC) solutions, by analyzing their rheological behavior, chemical-physical properties, and degradation resistance. HEC and HPC are widely used cellulose ethers with thickening, stabilizing, and water-retaining properties, making them valuable in cosmetics, electronics, pharmaceuticals, and other industries. However, these polymers degrade under harsh conditions and are prone to microbial contamination in aqueous systems. The results demonstrate that incorporating DND into cellulose ether formulations significantly enhances their stability and reduces biodegradation risks. Viscosity measurements show slower depolymerization rates in DND-containing dispersions, indicating a longer shelf life than pure HEC or HPC solutions. Additionally, pH fluctuations are more controlled in composites, with a maximum variation of only 1 pH unit compared to 2.5 units in standard solutions, suggesting improved chemical stability. Conductivity changes due to degradation are minimal in DND formulations, indicating reduced breakdown over time. Notably, microbial growth is drastically reduced in DND composites. These findings highlight DND's role in improving cellulose ether solutions' durability, functionality, and shelf life, offering significant benefits for industries that rely on these materials by ensuring enhanced product stability and prolonged performance.

Palmieri, E., Alabiso, A., Migliore, L., Mazzuca, C., Tamburri, E., Guglielmotti, V., et al. (2025). Enhancing stability: The protective role of nanodiamonds against biodegradation in cellulose ethers dispersions. POLYMER DEGRADATION AND STABILITY, 234 [10.1016/j.polymdegradstab.2025.111247].

Enhancing stability: The protective role of nanodiamonds against biodegradation in cellulose ethers dispersions

Palmieri E.
;
Alabiso A.;Migliore L.;Tamburri E.;Guglielmotti V.;Orlanducci S.
2025-01-01

Abstract

This study investigates the effect of detonation nanodiamonds (DND) in preserving cellulose dispersions, specifically hydroxyethyl cellulose (HEC) and hydroxypropyl cellulose (HPC) solutions, by analyzing their rheological behavior, chemical-physical properties, and degradation resistance. HEC and HPC are widely used cellulose ethers with thickening, stabilizing, and water-retaining properties, making them valuable in cosmetics, electronics, pharmaceuticals, and other industries. However, these polymers degrade under harsh conditions and are prone to microbial contamination in aqueous systems. The results demonstrate that incorporating DND into cellulose ether formulations significantly enhances their stability and reduces biodegradation risks. Viscosity measurements show slower depolymerization rates in DND-containing dispersions, indicating a longer shelf life than pure HEC or HPC solutions. Additionally, pH fluctuations are more controlled in composites, with a maximum variation of only 1 pH unit compared to 2.5 units in standard solutions, suggesting improved chemical stability. Conductivity changes due to degradation are minimal in DND formulations, indicating reduced breakdown over time. Notably, microbial growth is drastically reduced in DND composites. These findings highlight DND's role in improving cellulose ether solutions' durability, functionality, and shelf life, offering significant benefits for industries that rely on these materials by ensuring enhanced product stability and prolonged performance.
2025
Pubblicato
Rilevanza internazionale
Articolo
Esperti anonimi
Settore CHEM-03/A - Chimica generale e inorganica
English
Con Impact Factor ISI
Biodegradation
Cellulose ethers
Composites stability
Nanodiamond composites
Polymer stability
Palmieri, E., Alabiso, A., Migliore, L., Mazzuca, C., Tamburri, E., Guglielmotti, V., et al. (2025). Enhancing stability: The protective role of nanodiamonds against biodegradation in cellulose ethers dispersions. POLYMER DEGRADATION AND STABILITY, 234 [10.1016/j.polymdegradstab.2025.111247].
Palmieri, E; Alabiso, A; Migliore, L; Mazzuca, C; Tamburri, E; Guglielmotti, V; Orlanducci, S
Articolo su rivista
File in questo prodotto:
File Dimensione Formato  
Polymer Degradation and Stability 234 (2025) 111247.pdf

accesso aperto

Tipologia: Versione Editoriale (PDF)
Licenza: Creative commons
Dimensione 8.94 MB
Formato Adobe PDF
8.94 MB Adobe PDF Visualizza/Apri

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2108/415304
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus ND
  • ???jsp.display-item.citation.isi??? 0
social impact