This study investigates the effect of detonation nanodiamonds (DND) in preserving cellulose dispersions, specifically hydroxyethyl cellulose (HEC) and hydroxypropyl cellulose (HPC) solutions, by analyzing their rheological behavior, chemical-physical properties, and degradation resistance. HEC and HPC are widely used cellulose ethers with thickening, stabilizing, and water-retaining properties, making them valuable in cosmetics, electronics, pharmaceuticals, and other industries. However, these polymers degrade under harsh conditions and are prone to microbial contamination in aqueous systems. The results demonstrate that incorporating DND into cellulose ether formulations significantly enhances their stability and reduces biodegradation risks. Viscosity measurements show slower depolymerization rates in DND-containing dispersions, indicating a longer shelf life than pure HEC or HPC solutions. Additionally, pH fluctuations are more controlled in composites, with a maximum variation of only 1 pH unit compared to 2.5 units in standard solutions, suggesting improved chemical stability. Conductivity changes due to degradation are minimal in DND formulations, indicating reduced breakdown over time. Notably, microbial growth is drastically reduced in DND composites. These findings highlight DND's role in improving cellulose ether solutions' durability, functionality, and shelf life, offering significant benefits for industries that rely on these materials by ensuring enhanced product stability and prolonged performance.
Palmieri, E., Alabiso, A., Migliore, L., Mazzuca, C., Tamburri, E., Guglielmotti, V., et al. (2025). Enhancing stability: The protective role of nanodiamonds against biodegradation in cellulose ethers dispersions. POLYMER DEGRADATION AND STABILITY, 234 [10.1016/j.polymdegradstab.2025.111247].
Enhancing stability: The protective role of nanodiamonds against biodegradation in cellulose ethers dispersions
Palmieri E.
;Alabiso A.;Migliore L.;Tamburri E.;Guglielmotti V.;Orlanducci S.
2025-01-01
Abstract
This study investigates the effect of detonation nanodiamonds (DND) in preserving cellulose dispersions, specifically hydroxyethyl cellulose (HEC) and hydroxypropyl cellulose (HPC) solutions, by analyzing their rheological behavior, chemical-physical properties, and degradation resistance. HEC and HPC are widely used cellulose ethers with thickening, stabilizing, and water-retaining properties, making them valuable in cosmetics, electronics, pharmaceuticals, and other industries. However, these polymers degrade under harsh conditions and are prone to microbial contamination in aqueous systems. The results demonstrate that incorporating DND into cellulose ether formulations significantly enhances their stability and reduces biodegradation risks. Viscosity measurements show slower depolymerization rates in DND-containing dispersions, indicating a longer shelf life than pure HEC or HPC solutions. Additionally, pH fluctuations are more controlled in composites, with a maximum variation of only 1 pH unit compared to 2.5 units in standard solutions, suggesting improved chemical stability. Conductivity changes due to degradation are minimal in DND formulations, indicating reduced breakdown over time. Notably, microbial growth is drastically reduced in DND composites. These findings highlight DND's role in improving cellulose ether solutions' durability, functionality, and shelf life, offering significant benefits for industries that rely on these materials by ensuring enhanced product stability and prolonged performance.File | Dimensione | Formato | |
---|---|---|---|
Polymer Degradation and Stability 234 (2025) 111247.pdf
accesso aperto
Tipologia:
Versione Editoriale (PDF)
Licenza:
Creative commons
Dimensione
8.94 MB
Formato
Adobe PDF
|
8.94 MB | Adobe PDF | Visualizza/Apri |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.