A composite polymeric membrane to be used as electrolyte in polymer electrolyte membrane fuel cells has been prepared and characterized. The membrane is composed of an acidic polymer, sulfonated polyetheretherketone, and of basic filler, amino-diphenylsilandiol, a functionalized organically modified silane. Attenuated total reflectance (ATR)/fourier transform infrared spectroscopy (FTIR) demonstrated the occurrence of a specific interaction of the polymer ASO3H groups with the basic function of the filler. Such interaction reflected in reduced swelling, enhanced thermal stability, and good proton conductivity values at intermediate temperatures (r 10 2 S cm 1 at 100 C).
Ahmed, Z., Belitto, S., DI VONA, M.l., Trombetta, M., Traversa, E., Licoccia, S. (2012). Sulphonated Poly Ether Ether Ketone/Aminodiphenylsilandiol Composite Electrolyte for PEM Fuel Cells. JOURNAL OF APPLIED POLYMER SCIENCE, 124, 2610-2614 [10.1002/app.34906].
Sulphonated Poly Ether Ether Ketone/Aminodiphenylsilandiol Composite Electrolyte for PEM Fuel Cells
DI VONA, MARIA LUISA;TRAVERSA, ENRICO;LICOCCIA, SILVIA
2012-01-01
Abstract
A composite polymeric membrane to be used as electrolyte in polymer electrolyte membrane fuel cells has been prepared and characterized. The membrane is composed of an acidic polymer, sulfonated polyetheretherketone, and of basic filler, amino-diphenylsilandiol, a functionalized organically modified silane. Attenuated total reflectance (ATR)/fourier transform infrared spectroscopy (FTIR) demonstrated the occurrence of a specific interaction of the polymer ASO3H groups with the basic function of the filler. Such interaction reflected in reduced swelling, enhanced thermal stability, and good proton conductivity values at intermediate temperatures (r 10 2 S cm 1 at 100 C).| File | Dimensione | Formato | |
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