We consider a continuous system of classical particles confined in a cubic box Lambda interacting through a stable and finite range pair potential with an attractive tail. We study the Mayer series of the grand canonical pressure of the system p(Lambda)(omega)(ss,lambda) at inverse temperature ss and fugacity. in the presence of boundary conditions. belonging to a very large class of locally finite particle configurations. This class of allowed boundary conditions is the basis for any probability measure on the space of locally finite particle configurations satisfying the Ruelle estimates. We show that the p(Lambda)(omega)(ss,lambda) can be written as the sum of two terms. The first term, which is analytic and bounded as the fugacity. varies in a omega-independent and.-independent disk, coincides with the free-boundary-condition pressure in the thermodynamic limit. The second term, analytic in a omega-dependent convergence radius, goes to zero in the thermodynamic limit. As far as we know, this is the first rigorous analysis of the behavior of the Mayer series of a non-ideal gas subjected to non-free and non-periodic boundary conditions in the low-density/hightemperature regime when particles interact through a non-purely repulsive pair potential.

Fialho, P., de Lima, B., Procacci, A., Scoppola, B. (2023). On the analyticity of the pressure for a non-ideal gas with high density boundary conditions. JOURNAL OF MATHEMATICAL PHYSICS, 64(5) [10.1063/5.0136724].

On the analyticity of the pressure for a non-ideal gas with high density boundary conditions

Procacci A.
;
Scoppola B.
2023-01-01

Abstract

We consider a continuous system of classical particles confined in a cubic box Lambda interacting through a stable and finite range pair potential with an attractive tail. We study the Mayer series of the grand canonical pressure of the system p(Lambda)(omega)(ss,lambda) at inverse temperature ss and fugacity. in the presence of boundary conditions. belonging to a very large class of locally finite particle configurations. This class of allowed boundary conditions is the basis for any probability measure on the space of locally finite particle configurations satisfying the Ruelle estimates. We show that the p(Lambda)(omega)(ss,lambda) can be written as the sum of two terms. The first term, which is analytic and bounded as the fugacity. varies in a omega-independent and.-independent disk, coincides with the free-boundary-condition pressure in the thermodynamic limit. The second term, analytic in a omega-dependent convergence radius, goes to zero in the thermodynamic limit. As far as we know, this is the first rigorous analysis of the behavior of the Mayer series of a non-ideal gas subjected to non-free and non-periodic boundary conditions in the low-density/hightemperature regime when particles interact through a non-purely repulsive pair potential.
2023
Pubblicato
Rilevanza internazionale
Articolo
Esperti anonimi
Settore MATH-04/A - Fisica matematica
English
Con Impact Factor ISI
Phase transitions; Physics of gases; Thermodynamic functions; Power series; Interatomic potentials; Statistical mechanics; Statistical thermodynamics; Thermodynamic limit
Fialho, P., de Lima, B., Procacci, A., Scoppola, B. (2023). On the analyticity of the pressure for a non-ideal gas with high density boundary conditions. JOURNAL OF MATHEMATICAL PHYSICS, 64(5) [10.1063/5.0136724].
Fialho, Pms; de Lima, Bnb; Procacci, A; Scoppola, B
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2108/391252
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