1,2,4-Triferrocenylbenzene was isolated and fully characterized for the first time. It was obtained, together with 1,3,5-triferrocenylbenzene, by cyclotrimerization reaction, catalyzed either by metalloporphyrins or cobaltocene. The latter catalyst gave better results. The isomerically different triferrocenylbenzenes exhibit different properties.
Fiorentini, S., Floris, B., Galloni, P., Grepioni, F., Polito, M., Tagliatesta, P. (2006). The metal-catalyzed cyclotrimerization of ferrocenylethyne: preparation and characterization of 1,2,4-triferrocenylbenzene. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY(7), 1726-1732 [10.1002/ejoc.200500896].
The metal-catalyzed cyclotrimerization of ferrocenylethyne: preparation and characterization of 1,2,4-triferrocenylbenzene
FLORIS, BARBARA;GALLONI, PIERLUCA;TAGLIATESTA, PIETRO
2006-01-01
Abstract
1,2,4-Triferrocenylbenzene was isolated and fully characterized for the first time. It was obtained, together with 1,3,5-triferrocenylbenzene, by cyclotrimerization reaction, catalyzed either by metalloporphyrins or cobaltocene. The latter catalyst gave better results. The isomerically different triferrocenylbenzenes exhibit different properties.File in questo prodotto:
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