2D transition metal carbides and nitrides (MXenes) open up novel opportunities in gas sensing with high sensitivity at room temperature. Herein, 2D Mo2CTx flakes with high aspect ratio are successfully synthesized. The chemiresistive effect in a sub-mu m MXene multilayer for different organic vapors and humidity at 10(1)-10(4) ppm in dry air is studied. Reasonably, the low-noise resistance signal allows the detection of H2O down to 10 ppm. Moreover, humidity suppresses the response of Mo2CTx to organic analytes due to the blocking of adsorption active sites. By measuring the impedance of MXene layers as a function of ac frequency in the 10(-2)-10(6) Hz range, it is shown that operation principle of the sensor is dominated by resistance change rather than capacitance variations. The sensor transfer function allows to conclude that the Mo2CTx chemiresistance is mainly originating from electron transport through interflake potential barriers with heights up to 0.2 eV. Density functional theory calculations, elucidating the Mo2C surface interaction with organic analytes and H2O, explain the experimental data as an energy shift of the density of states under the analyte's adsorption which induces increasing electrical resistance.

Pazniak, H., Varezhnikov, A.s., Kolosov, D.a., Plugin, I.a., Vito, A.d., Glukhova, O.e., et al. (2021). 2D Molybdenum Carbide MXenes for Enhanced Selective Detection of Humidity in Air. ADVANCED MATERIALS, 33(52) [10.1002/adma.202104878].

2D Molybdenum Carbide MXenes for Enhanced Selective Detection of Humidity in Air

Vito, Alessia Di;
2021-12-01

Abstract

2D transition metal carbides and nitrides (MXenes) open up novel opportunities in gas sensing with high sensitivity at room temperature. Herein, 2D Mo2CTx flakes with high aspect ratio are successfully synthesized. The chemiresistive effect in a sub-mu m MXene multilayer for different organic vapors and humidity at 10(1)-10(4) ppm in dry air is studied. Reasonably, the low-noise resistance signal allows the detection of H2O down to 10 ppm. Moreover, humidity suppresses the response of Mo2CTx to organic analytes due to the blocking of adsorption active sites. By measuring the impedance of MXene layers as a function of ac frequency in the 10(-2)-10(6) Hz range, it is shown that operation principle of the sensor is dominated by resistance change rather than capacitance variations. The sensor transfer function allows to conclude that the Mo2CTx chemiresistance is mainly originating from electron transport through interflake potential barriers with heights up to 0.2 eV. Density functional theory calculations, elucidating the Mo2C surface interaction with organic analytes and H2O, explain the experimental data as an energy shift of the density of states under the analyte's adsorption which induces increasing electrical resistance.
dic-2021
Pubblicato
Rilevanza internazionale
Articolo
Esperti anonimi
Settore ING-INF/01
English
DFT
Mo 2CT x
alcohol
chemiresistor
humidity
multisensor array
vdW-DF
Pazniak, H., Varezhnikov, A.s., Kolosov, D.a., Plugin, I.a., Vito, A.d., Glukhova, O.e., et al. (2021). 2D Molybdenum Carbide MXenes for Enhanced Selective Detection of Humidity in Air. ADVANCED MATERIALS, 33(52) [10.1002/adma.202104878].
Pazniak, H; Varezhnikov, As; Kolosov, Da; Plugin, Ia; Vito, Ad; Glukhova, Oe; Sheverdyaeva, Pm; Spasova, M; Kaikov, I; Kolesnikov, Ea; Moras, P; Bainy...espandi
Articolo su rivista
File in questo prodotto:
File Dimensione Formato  
04_AdvancedMaterials2021.pdf

accesso aperto

Tipologia: Versione Editoriale (PDF)
Licenza: Creative commons
Dimensione 2.75 MB
Formato Adobe PDF
2.75 MB Adobe PDF Visualizza/Apri

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2108/345805
Citazioni
  • ???jsp.display-item.citation.pmc??? 10
  • Scopus 60
  • ???jsp.display-item.citation.isi??? 55
social impact