Biological/metal oxide composite transport layers cast from green solvents for boosting light harvesting response of organic photovoltaic cells indoors

Organic solar cells with biological/metal-oxide electron transport layers (ETLs), consisting of a ZnO compact layer covered by a thin DNA layer, both of which deposited with green solvents (water or water/alcohols mixtures) are presented for application under low intensity indoor lighting. Under white LED lamp (200, 400 lx), photovoltaic cells with P3HT:PC70BM polymer semiconductor blends delivered an average maximum power density (MPD) of 8.7 μW cm-2, corresponding to a power conversion efficiency, PCE, of = 8.56% (PCE of best cell was 8.74%). The ZnO/DNA bilayer boosted efficiency by 68% and 13% in relative terms compared to cells made with DNA-only and ZnO-only ETLs at 400 lx. Photovoltaic cells with ZnO/DNA composite ETLs based on PTB7:PC70BM blends, that absorb a broader range of the indoor lighting spectrum, delivered MPDs of 16.2 μW cm-2 with an estimated average PCE of 14.3% (best cell efficiency of 15.8%) at 400 lx. The best efficiencies for cells fabricated on flexible plastic substrates were 11.9% at 400 lx. This is the first report in which polymer photovoltaics incorporating biological materials have shown to increment performance at these low light levels and work very efficiently under indoor artificial light illumination. The finding can be useful for the production of more bio-compatible photovoltaics as well as bio-sensing devices based on organic semiconductors.