Improved hydrolytic and mechanical stability of sulfonated aromatic proton exchange membranes reinforced by electrospun PPSU fibers

The hydrolytic stability of ionomer membranes is a matter of concern for the long-term durability of energy storage and conversion devices. Various reinforcement strategies exist for the improvement of the performances of the overall membrane. We propose in this article the stabilization of membranes based on aromatic ion conducting polymers (SPEEK and SPPSU) by the introduction of an electrospun mat of inexpensive PPSU polymer. Characterization data from hydrolytic stability (mass uptake and dimension change) and from mechanical and conductivity measurements show an improved stability of membranes in phosphate buffer, used for enzymatic fuel cells, and in distilled water. The synergistic effect of the reinforcement, together with the casting solvent and the thermal treatment or blending polymers, is promising for the realization of high stability ionomer membranes.