This Concept is focused on the key features of dissipative dynamic combinatorial chemistry (DDCC). DDCC deals with transient libraries of compounds, maintained out-of-equilibrium by the consumption of a fuel, whose composition changes upon the selection pressure of kinetic and/or thermodynamic processes. Concepts and definitions of kinetic and thermodynamic dissipative dynamic libraries ("KDDL" and "TDDL"), are introduced and illustrated by a number of actual cases, thus showing the consistency of the present approach. Such concepts and definitions can help establish a common language for this emerging field, which, in our view, has the potential to become highly relevant to supramolecular chemistry.

Del Giudice, D., Spatola, E., Valentini, M., Ercolani, G., Di Stefano, S. (2022). Dissipative Dynamic Libraries (DDLs) and Dissipative Dynamic Combinatorial Chemistry (DDCC). CHEMSYSTEMSCHEM, 4(6) [10.1002/syst.202200023].

Dissipative Dynamic Libraries (DDLs) and Dissipative Dynamic Combinatorial Chemistry (DDCC)

Ercolani, G
;
2022-01-01

Abstract

This Concept is focused on the key features of dissipative dynamic combinatorial chemistry (DDCC). DDCC deals with transient libraries of compounds, maintained out-of-equilibrium by the consumption of a fuel, whose composition changes upon the selection pressure of kinetic and/or thermodynamic processes. Concepts and definitions of kinetic and thermodynamic dissipative dynamic libraries ("KDDL" and "TDDL"), are introduced and illustrated by a number of actual cases, thus showing the consistency of the present approach. Such concepts and definitions can help establish a common language for this emerging field, which, in our view, has the potential to become highly relevant to supramolecular chemistry.
2022
Pubblicato
Rilevanza internazionale
Articolo
Esperti anonimi
Settore CHIM/06
English
Systems chemistry
Dissipative systems
Dynamic covalent chemistry
Dynamic libraries
Chemical fuels
Del Giudice, D., Spatola, E., Valentini, M., Ercolani, G., Di Stefano, S. (2022). Dissipative Dynamic Libraries (DDLs) and Dissipative Dynamic Combinatorial Chemistry (DDCC). CHEMSYSTEMSCHEM, 4(6) [10.1002/syst.202200023].
Del Giudice, D; Spatola, E; Valentini, M; Ercolani, G; Di Stefano, S
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2108/311757
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