We report on the magnetic coupling between isolated Co atoms as well as small Co islands and Ni(111) mediated by an epitaxial graphene layer. X-ray magnetic circular dichroism and scanning tunneling microscopy combined with density functional theory calculations reveal that Co atoms occupy two distinct adsorption sites, with different magnetic coupling to the underlying Ni(111) surface. We further report a transition from an antiferromagnetic to a ferromagnetic coupling with increasing Co cluster size. Our results highlight the extreme sensitivity of the exchange interaction mediated by graphene to the adsorption site and to the in-plane coordination of the magnetic atoms.

Barla, A., Bellini, V., Rusponi, S., Ferriani, P., Pivetta, M., Donati, F., et al. (2016). Complex magnetic exchange coupling between Co nanostructures and Ni(111) across epitaxial graphene. ACS NANO, 10(1), 1101-1107 [10.1021/acsnano.5b06410].

Complex magnetic exchange coupling between Co nanostructures and Ni(111) across epitaxial graphene

Persichetti, Luca;
2016-01-01

Abstract

We report on the magnetic coupling between isolated Co atoms as well as small Co islands and Ni(111) mediated by an epitaxial graphene layer. X-ray magnetic circular dichroism and scanning tunneling microscopy combined with density functional theory calculations reveal that Co atoms occupy two distinct adsorption sites, with different magnetic coupling to the underlying Ni(111) surface. We further report a transition from an antiferromagnetic to a ferromagnetic coupling with increasing Co cluster size. Our results highlight the extreme sensitivity of the exchange interaction mediated by graphene to the adsorption site and to the in-plane coordination of the magnetic atoms.
Pubblicato
Rilevanza internazionale
Articolo
Esperti anonimi
Settore FIS/03
English
Density functional theory (DFT); Graphene; Magnetic exchange interaction; Scanning tunneling microscopy (STM); X-ray magnetic circular dichroism (XMCD); Materials Science (all); Engineering (all); Physics and Astronomy (all)
Barla, A., Bellini, V., Rusponi, S., Ferriani, P., Pivetta, M., Donati, F., et al. (2016). Complex magnetic exchange coupling between Co nanostructures and Ni(111) across epitaxial graphene. ACS NANO, 10(1), 1101-1107 [10.1021/acsnano.5b06410].
Barla, A; Bellini, V; Rusponi, S; Ferriani, P; Pivetta, M; Donati, F; Patthey, F; Persichetti, L; Mahatha, Sk; Papagno, M; Piamonteze, C; Fichtner, S; Heinze, S; Gambardella, P; Brune, H; Carbone, C
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2108/300658
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