It has been recently shown that pressure may affect the mesoscopic heterogeneity in aprotic ionic liquids, owing to the long alkyl chain folding on itself. Here we explore protic ionic liquids, using classical molecular dynamics. These compounds have shorter and stiffer alkyl chains, harder to fold. We observed that high pressure affects the mesoscopic structure of the studied chemicals and, indeed, the effect may be ascribed to chain folding.

Mariani, A., Caminiti, R., Campetella, M., Gontrani, L. (2016). Pressure-induced mesoscopic disorder in protic ionic liquids: first computational study. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 18(4), 2297-2302 [10.1039/c5cp06800b].

Pressure-induced mesoscopic disorder in protic ionic liquids: first computational study

Gontrani, L.
Writing – Review & Editing
2016-01-01

Abstract

It has been recently shown that pressure may affect the mesoscopic heterogeneity in aprotic ionic liquids, owing to the long alkyl chain folding on itself. Here we explore protic ionic liquids, using classical molecular dynamics. These compounds have shorter and stiffer alkyl chains, harder to fold. We observed that high pressure affects the mesoscopic structure of the studied chemicals and, indeed, the effect may be ascribed to chain folding.
2016
Pubblicato
Rilevanza internazionale
Articolo
Esperti anonimi
Settore CHIM/02 - CHIMICA FISICA
English
Con Impact Factor ISI
Mariani, A., Caminiti, R., Campetella, M., Gontrani, L. (2016). Pressure-induced mesoscopic disorder in protic ionic liquids: first computational study. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 18(4), 2297-2302 [10.1039/c5cp06800b].
Mariani, A; Caminiti, R; Campetella, M; Gontrani, L
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2108/294597
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