A rigid ferrocene-fullerene dyad was obtained from fullerene (C-60), N-methylglycine and 1,1'-(alpha-oxotrimethylene)ferrocene. The frozen geometry resulted in an enhanced electron transfer rate from ferrocene to fullerene moieties, when compared with conformationally flexible N-methyl-2-ferrocenylfulleropyrrolidine. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006).
Caporossi, F., Floris, B., Galloni, P., Gatto, E., Venanzi, M. (2006). Enhanced electron transfer rate in a rigid ferrocene-fulleropyrrolidine dyad. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY(19), 4362-4366 [10.1002/ejoc.200600318].
Enhanced electron transfer rate in a rigid ferrocene-fulleropyrrolidine dyad
FLORIS, BARBARA;GALLONI, PIERLUCA
;GATTO, EMANUELA
;VENANZI, MARIANO
2006-01-01
Abstract
A rigid ferrocene-fullerene dyad was obtained from fullerene (C-60), N-methylglycine and 1,1'-(alpha-oxotrimethylene)ferrocene. The frozen geometry resulted in an enhanced electron transfer rate from ferrocene to fullerene moieties, when compared with conformationally flexible N-methyl-2-ferrocenylfulleropyrrolidine. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006).| File | Dimensione | Formato | |
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