In a recent Science paper, Stahl and co-workers describe direct C(sp3)−H methylation via Ni-catalyzed cross-coupling of a radical pair deriving from divergent hydrogen atom transfer (HAT) and C–Me cleavage pathways in a photogenerated alkoxyl radical. The implications of these findings for the rapidly expanding field of C−H methylation are discussed.
Olivo, G., Bietti, M. (2021). Aliphatic C-H bond methylation enabled by hydrogen atom transfer. CHEM, 7(6), 1427-1430 [10.1016/j.chempr.2021.05.016].
Aliphatic C-H bond methylation enabled by hydrogen atom transfer
Bietti, M
2021-01-01
Abstract
In a recent Science paper, Stahl and co-workers describe direct C(sp3)−H methylation via Ni-catalyzed cross-coupling of a radical pair deriving from divergent hydrogen atom transfer (HAT) and C–Me cleavage pathways in a photogenerated alkoxyl radical. The implications of these findings for the rapidly expanding field of C−H methylation are discussed.File in questo prodotto:
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