The coupling of mass spectrometry with ionization techniques like electrospray ionization (ESI) or matrix-assisted matrix-assisted laser desorption-ionization (MALDI) offers many advantages over other well-established spectroscopic techniques employed for the investigation of intermediates or short-lived species in condensed-phase. In this review we describe some of the applications of mass spectrometry, in particular of ESI-MS to the detection and characterization of high-valent metal-oxo, -peroxo and -peroxy derivatives, crucial intermediates in the oxyfunctionalization of organic substrates. In addition, by utilizing gas-phase ion-molecule reactions and MS/MS experiments, information on the intrinsic reactivity of the short-lived intermediates may be obtained. The combined use of ESI-MS in association with other spectroscopic techniques and theoretical calculations is discussed as well. © 2006 Wiley Periodicals, Inc.

Bortolini, O., Conte, V. (2006). Mass spectrometric characterization of high-valent metal-oxo, -peroxo and -peroxy intermediates of relevance in oxidation processes. MASS SPECTROMETRY REVIEWS, 25(5), 724-740 [10.1002/mas.20085].

Mass spectrometric characterization of high-valent metal-oxo, -peroxo and -peroxy intermediates of relevance in oxidation processes

CONTE, VALERIA
2006-01-01

Abstract

The coupling of mass spectrometry with ionization techniques like electrospray ionization (ESI) or matrix-assisted matrix-assisted laser desorption-ionization (MALDI) offers many advantages over other well-established spectroscopic techniques employed for the investigation of intermediates or short-lived species in condensed-phase. In this review we describe some of the applications of mass spectrometry, in particular of ESI-MS to the detection and characterization of high-valent metal-oxo, -peroxo and -peroxy derivatives, crucial intermediates in the oxyfunctionalization of organic substrates. In addition, by utilizing gas-phase ion-molecule reactions and MS/MS experiments, information on the intrinsic reactivity of the short-lived intermediates may be obtained. The combined use of ESI-MS in association with other spectroscopic techniques and theoretical calculations is discussed as well. © 2006 Wiley Periodicals, Inc.
Pubblicato
Rilevanza internazionale
Articolo
Esperti anonimi
Settore CHIM/06 - Chimica Organica
English
Con Impact Factor ISI
ESI; MALDI; Mass spectrometry; Metal-peroxo; Metal-peroxy; Metaloxo; Oxidation processes; Reaction intermediates
http://onlinelibrary.wiley.com/doi/10.1002/mas.20085/epdf
Bortolini, O., Conte, V. (2006). Mass spectrometric characterization of high-valent metal-oxo, -peroxo and -peroxy intermediates of relevance in oxidation processes. MASS SPECTROMETRY REVIEWS, 25(5), 724-740 [10.1002/mas.20085].
Bortolini, O; Conte, V
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2108/27762
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