In this account, the author describes the synthetic efforts of his group on the preparation and functionalization of corrole derivatives. The work started with beta-alkylcorroles and continued with the preparation of 5,10,15-triarylcorroles. The peripheral functionalization of both the beta-alkyl- and meso-triarylcorroles is described, together with several examples of the intriguing and unexpected reactivity of this deceptive macrocycle in these reactions.
Paolesse, R. (2008). Corrole: The little big porphyrinoid. SYNLETT(15), 2215-2230 [10.1055/s-2008-1078687].
Corrole: The little big porphyrinoid
PAOLESSE, ROBERTO
2008-01-01
Abstract
In this account, the author describes the synthetic efforts of his group on the preparation and functionalization of corrole derivatives. The work started with beta-alkylcorroles and continued with the preparation of 5,10,15-triarylcorroles. The peripheral functionalization of both the beta-alkyl- and meso-triarylcorroles is described, together with several examples of the intriguing and unexpected reactivity of this deceptive macrocycle in these reactions.File in questo prodotto:
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