We show here that the recently reported surprisingly large association constant (K = 7.6 x 10(4) M-1) between azulene and [60]fullerene is due to experimental artifacts, pointing out potential errors in the characterization of association equilibria by fluorescence spectroscopy, and suggesting the best experimental practices.
Stella, L., Capodilupo, A.l., Bietti, M. (2008). A reassessment of the association between azulene and [60]fullerene. Possible pitfalls in the determination of binding constants through fluorescence spectroscopy. CHEMICAL COMMUNICATIONS(39), 4744-4746 [10.1039/b808357f].
A reassessment of the association between azulene and [60]fullerene. Possible pitfalls in the determination of binding constants through fluorescence spectroscopy
STELLA, LORENZO;CAPODILUPO, AGOSTINA LINA;BIETTI, MASSIMO
2008-01-01
Abstract
We show here that the recently reported surprisingly large association constant (K = 7.6 x 10(4) M-1) between azulene and [60]fullerene is due to experimental artifacts, pointing out potential errors in the characterization of association equilibria by fluorescence spectroscopy, and suggesting the best experimental practices.File in questo prodotto:
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