Detonation nanodiamonds (DNDs) were functionalized by ruthenium porphyrins and used as catalysts in the cyclopropanation reaction of olefins. The heterogeneous catalyst was characterized by transmission electron microscopy (TEM), scanning electron microscopy (SEM), and XPS (X-ray photoelectron spectroscopy). The XPS was used to control the binding of the ruthenium porphyrin to the DNDs' surface. This catalyst was used in the cyclopropanation reactions of simple olefins and was reused with no loss of activity in four consecutive cycles, after recovering each time by simple centrifugation.

Lorecchio, C., Tamburri, E., Lazzarini, L., Orlanducci, S., Zanoni, R., Tagliatesta, P. (2020). Covalent functionalization of nanodiamonds by Ruthenium porphyrin, and their catalytic activity in the cyclopropanation reaction of olefins. CATALYSTS, 10(6), 666 [10.3390/catal10060666].

Covalent functionalization of nanodiamonds by Ruthenium porphyrin, and their catalytic activity in the cyclopropanation reaction of olefins

Lorecchio, C;Tamburri, E;Orlanducci, S;Tagliatesta, P
2020-01-01

Abstract

Detonation nanodiamonds (DNDs) were functionalized by ruthenium porphyrins and used as catalysts in the cyclopropanation reaction of olefins. The heterogeneous catalyst was characterized by transmission electron microscopy (TEM), scanning electron microscopy (SEM), and XPS (X-ray photoelectron spectroscopy). The XPS was used to control the binding of the ruthenium porphyrin to the DNDs' surface. This catalyst was used in the cyclopropanation reactions of simple olefins and was reused with no loss of activity in four consecutive cycles, after recovering each time by simple centrifugation.
2020
Pubblicato
Rilevanza internazionale
Articolo
Esperti anonimi
Settore CHIM/03 - CHIMICA GENERALE E INORGANICA
English
nanodiamonds
metalloporphyrin
catalysts
cyclopropanation reaction
olefins
https://www.mdpi.com/2073-4344/10/6/666
Lorecchio, C., Tamburri, E., Lazzarini, L., Orlanducci, S., Zanoni, R., Tagliatesta, P. (2020). Covalent functionalization of nanodiamonds by Ruthenium porphyrin, and their catalytic activity in the cyclopropanation reaction of olefins. CATALYSTS, 10(6), 666 [10.3390/catal10060666].
Lorecchio, C; Tamburri, E; Lazzarini, L; Orlanducci, S; Zanoni, R; Tagliatesta, P
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2108/258535
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