PGMA polymer brushes are successfully grown on the inner wall of a microreactor to give a nanostructure. The oxirane groups of the brushes are used for the anchoring of a catalyst. The utility of the combination of catalyst-functionatized brushes and a microreactor is clearly demonstrated for the TBD-catalyzed Knoevenagel condensation reaction of benzaldehyde and malononitrile.
Costantini, F., Bula, W.p., Salvio, R., Huskens, J., Gardeniers, H., Reinhoudt, D.n., et al. (2009). Nanostructure based on polymer brushes for efficient heterogeneous catalysis in microreactors. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 131(5), 1650-1651 [10.1021/ja807616z].
Nanostructure based on polymer brushes for efficient heterogeneous catalysis in microreactors
Salvio R.;
2009-01-01
Abstract
PGMA polymer brushes are successfully grown on the inner wall of a microreactor to give a nanostructure. The oxirane groups of the brushes are used for the anchoring of a catalyst. The utility of the combination of catalyst-functionatized brushes and a microreactor is clearly demonstrated for the TBD-catalyzed Knoevenagel condensation reaction of benzaldehyde and malononitrile.| File | Dimensione | Formato | |
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2009 JACS - Costantini Salvio - Microfluidics.pdf
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