Calix[4]arenes derivatives 1 and 2, featuring two guanidine units at the upper rim, catalyze the transesterification of diribonucleoside monophosphates much more effectively than that of HPNP. Rate accelerations relative to the background range from 10(3) to 10(4)-fold, and approach 10(5)-fold with the most favorable substrate-catalyst combinations.
Salvio, R., Cacciapaglia, R., Mandolini, L., Sansone, F., Casnati, A. (2014). Diguanidinocalix[4]arenes as effective and selective catalysts of the cleavage of diribonucleoside monophosphates. RSC ADVANCES, 4(65), 34412-34416 [10.1039/c4ra05751a].
Diguanidinocalix[4]arenes as effective and selective catalysts of the cleavage of diribonucleoside monophosphates
Salvio R.
;
2014-01-01
Abstract
Calix[4]arenes derivatives 1 and 2, featuring two guanidine units at the upper rim, catalyze the transesterification of diribonucleoside monophosphates much more effectively than that of HPNP. Rate accelerations relative to the background range from 10(3) to 10(4)-fold, and approach 10(5)-fold with the most favorable substrate-catalyst combinations.File in questo prodotto:
| File | Dimensione | Formato | |
|---|---|---|---|
|
Salvio dinucl RSC Adv 2014.pdf
solo utenti autorizzati
Tipologia:
Versione Editoriale (PDF)
Licenza:
Copyright dell'editore
Dimensione
258.58 kB
Formato
Adobe PDF
|
258.58 kB | Adobe PDF | Visualizza/Apri Richiedi una copia |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
