Assessment of the perturbed matrix method (PMM) ability in reproducing valence UV absorption spectra is carried out on two model systems: 1,2,3-triazine in methanol solution and uracil in water solution. Results show that even using the simplest definition of the quantum center, i.e. the portion of the system explicitly treated quantum mechanically, PMM provides rather good results. This paper further confirms the possibility of using PMM as a theoretical-computational tool, complementary to other methodologies, for addressing the electronic properties in molecular systems of high complexity.
Zazza, C., Amadei, A., Sanna, N., Grandi, A., Chillemi, G., Di Nola, A., et al. (2006). Theoretical modeling of the valence UV spectra of 1,2,3-triazine and uracil in solution. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 8(12), 1385-1393.
Tipologia: | Articolo su rivista |
Citazione: | Zazza, C., Amadei, A., Sanna, N., Grandi, A., Chillemi, G., Di Nola, A., et al. (2006). Theoretical modeling of the valence UV spectra of 1,2,3-triazine and uracil in solution. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 8(12), 1385-1393. |
Lingua: | English |
Settore Scientifico Disciplinare: | Settore CHIM/02 - Chimica Fisica |
Revisione (peer review): | Sì, ma tipo non specificato |
Tipo: | Articolo |
Rilevanza: | Rilevanza internazionale |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1039/b515678c |
Stato di pubblicazione: | Pubblicato |
Data di pubblicazione: | 2006 |
Titolo: | Theoretical modeling of the valence UV spectra of 1,2,3-triazine and uracil in solution |
Autori: | |
Autori: | Zazza, C; Amadei, A; Sanna, N; Grandi, A; Chillemi, G; Di Nola, A; D'Abramo, M; Aschi, M |
Appare nelle tipologie: | 01 - Articolo su rivista |