A series of 5,10,15-triarylcorroles has been prepared, with the meso-aryl rings functionalized with different substituents to investigate their influence on the aryl ring rotation with respect to the corrole plane. The study has been carried out by different NMR techniques, allowing the complete assignment of the 1H NMR spectra and giving insights on the kinetic and thermodynamic factors driving the atropisomerism in triarylcorrole derivatives.

BISCHETTI, M., Pomarico, G., Nardis, S., Mandoj, F., Cicero, D.O., & Paolesse, R. (2020). 5,10,15-Triarylcorrole atropisomerism. JOURNAL OF PORPHYRINS AND PHTHALOCYANINES [10.1142/S1088424619500706].

5,10,15-Triarylcorrole atropisomerism

BISCHETTI, MARTINA;G. Pomarico;S. Nardis;F. Mandoj;D. O. Cicero;R. Paolesse
2020

Abstract

A series of 5,10,15-triarylcorroles has been prepared, with the meso-aryl rings functionalized with different substituents to investigate their influence on the aryl ring rotation with respect to the corrole plane. The study has been carried out by different NMR techniques, allowing the complete assignment of the 1H NMR spectra and giving insights on the kinetic and thermodynamic factors driving the atropisomerism in triarylcorrole derivatives.
In corso di stampa
Rilevanza internazionale
Articolo
Esperti anonimi
Settore CHIM/07 - Fondamenti Chimici delle Tecnologie
eng
corrole, atropisomerism, NMR, aryl-ring rotation
BISCHETTI, M., Pomarico, G., Nardis, S., Mandoj, F., Cicero, D.O., & Paolesse, R. (2020). 5,10,15-Triarylcorrole atropisomerism. JOURNAL OF PORPHYRINS AND PHTHALOCYANINES [10.1142/S1088424619500706].
Bischetti, M; Pomarico, G; Nardis, S; Mandoj, F; Cicero, Do; Paolesse, R
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2108/216131
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