Two different copper and gallium arylcorroles have been functionalized using the Vilsmeier–Haack reaction. A further Knoevenagel reaction with cyanoacetic acid was performed on both complexes, affording the desired products with yields above 90 %. The newly synthesized compounds have been thoroughly characterized by a combination of spectroscopic methods, optical analyses, and X-ray crystallography. Moreover, they have been tested as anchoring groups for the hydrothermal synthesis of ZnO nanoparticles. The morphology of the heterogeneous composites has been studied by SEM, EDS and fluorescence microscopy analyses, thus confirming the presence of the corrole macrocycle in the hybrid material. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Berionni Berna, B., Savoldelli, A., Pomarico, G., Zurlo, F., Magna, G., Paolesse, R., et al. (2019). Grafting Copper and Gallium Corroles onto Zinc Oxide Nanoparticles. CHEMPLUSCHEM, 84(2), 154-160 [10.1002/cplu.201800576].

Grafting Copper and Gallium Corroles onto Zinc Oxide Nanoparticles

Berionni Berna B.;Savoldelli A.;Pomarico G.;Zurlo F.;Magna G.;Paolesse R.;Nardis S.
2019

Abstract

Two different copper and gallium arylcorroles have been functionalized using the Vilsmeier–Haack reaction. A further Knoevenagel reaction with cyanoacetic acid was performed on both complexes, affording the desired products with yields above 90 %. The newly synthesized compounds have been thoroughly characterized by a combination of spectroscopic methods, optical analyses, and X-ray crystallography. Moreover, they have been tested as anchoring groups for the hydrothermal synthesis of ZnO nanoparticles. The morphology of the heterogeneous composites has been studied by SEM, EDS and fluorescence microscopy analyses, thus confirming the presence of the corrole macrocycle in the hybrid material. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
Pubblicato
Rilevanza internazionale
Articolo
Esperti anonimi
Settore CHIM/07 - Fondamenti Chimici delle Tecnologie
eng
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https://www.scopus.com/inward/record.uri?eid=2-s2.0-85062157822&doi=10.1002/cplu.201800576&partnerID=40&md5=2fcecb8f6ced489cd00d47abd6e0249e
Berionni Berna, B., Savoldelli, A., Pomarico, G., Zurlo, F., Magna, G., Paolesse, R., et al. (2019). Grafting Copper and Gallium Corroles onto Zinc Oxide Nanoparticles. CHEMPLUSCHEM, 84(2), 154-160 [10.1002/cplu.201800576].
Berionni Berna, B; Savoldelli, A; Pomarico, G; Zurlo, F; Magna, G; Paolesse, R; Fronczek, Fr; Smith, Km; Nardis, S
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2108/210796
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