Copper and gallium β-acrolein corroles have been obtained by reaction of corrole complexes with 3-(dimethylamino)-acrolein/phosphoryl chloride (3-DMA/POCl3) under Vilsmeier conditions. In the case of the Ga complex, up to four acroleyl substituents have been introduced at the β-peripheral positions of the corrole macrocycle. The introduction of the acroleyl moiety on the corrole scaffold strongly influences the photophysical behaviour of the Ga corroles.
Savoldelli, A., Nardis, S., Genovese, D., Prodi, L., Fronczek, F.r., Smith, K.m., et al. (2018). Moving corrole towards a red-record: synthesis of β-acrolein Ga and Cu corroles using the Vilsmeier reaction. NEW JOURNAL OF CHEMISTRY, 42(10), 8200-8206 [10.1039/C7NJ04705C].
Moving corrole towards a red-record: synthesis of β-acrolein Ga and Cu corroles using the Vilsmeier reaction
Savoldelli, A.;Nardis, S.
;Paolesse, R.
2018-01-01
Abstract
Copper and gallium β-acrolein corroles have been obtained by reaction of corrole complexes with 3-(dimethylamino)-acrolein/phosphoryl chloride (3-DMA/POCl3) under Vilsmeier conditions. In the case of the Ga complex, up to four acroleyl substituents have been introduced at the β-peripheral positions of the corrole macrocycle. The introduction of the acroleyl moiety on the corrole scaffold strongly influences the photophysical behaviour of the Ga corroles.| File | Dimensione | Formato | |
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