The synthesis of the first examples of calix[4]arene-based Fischer carbene complexes is reported here. Fischer carbene complex 2 is the key intermediate to reach uracil-like derivatives 3 and 4. X-ray and NMR studies revealed that the uracyl-like synthon gives rise to a supramolecular dimer. The organometallic calixarene complexes showed a promising cytotoxicity towards human tumor cell lines.
D'Acunto, M., Tommasone, S., Talotta, C., Brancatelli, G., Geremia, S., Valletta, E., et al. (2016). Installing tungsten Fischer carbene complexes into a calixarene framework. RSC ADVANCES, 6(78), 75002-75005 [10.1039/C6RA17326H].
Installing tungsten Fischer carbene complexes into a calixarene framework
MACCHI, BEATRICE;
2016-01-01
Abstract
The synthesis of the first examples of calix[4]arene-based Fischer carbene complexes is reported here. Fischer carbene complex 2 is the key intermediate to reach uracil-like derivatives 3 and 4. X-ray and NMR studies revealed that the uracyl-like synthon gives rise to a supramolecular dimer. The organometallic calixarene complexes showed a promising cytotoxicity towards human tumor cell lines.| File | Dimensione | Formato | |
|---|---|---|---|
|
D' Acuto RSC Advances.pdf
solo utenti autorizzati
Descrizione: articolo
Licenza:
Copyright dell'editore
Dimensione
425.05 kB
Formato
Adobe PDF
|
425.05 kB | Adobe PDF | Visualizza/Apri Richiedi una copia |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
