Reaction of 2-amino-3-(pyrrol-1-yl)-5,10,15-tris(4-tert-butylphenyl)corrolato copper(II) with arylaldehydes affords novel π-extended β,β′-pyrrolo(1,2-a)pyrazino-fused corroles via a Pictet–Spengler reaction. Corrole shows an unprecedented reaction pathway, leading to a mixture of phenyl-substituted and nonsubstituted pyrrolopyrazino annulated species as reaction products.
Berionni Berna, B., Nardis, S., Galloni, P., Savoldelli, A., Stefanelli, M., Fronczek, F., et al. (2016). β-Pyrrolopyrazino Annulated Corroles via a Pictet-Spengler Approach. ORGANIC LETTERS, 18(14), 3318-3321 [10.1021/acs.orglett.6b01314].
β-Pyrrolopyrazino Annulated Corroles via a Pictet-Spengler Approach
NARDIS, SARA;GALLONI, PIERLUCA;STEFANELLI, MANUELA;PAOLESSE, ROBERTO
2016-01-01
Abstract
Reaction of 2-amino-3-(pyrrol-1-yl)-5,10,15-tris(4-tert-butylphenyl)corrolato copper(II) with arylaldehydes affords novel π-extended β,β′-pyrrolo(1,2-a)pyrazino-fused corroles via a Pictet–Spengler reaction. Corrole shows an unprecedented reaction pathway, leading to a mixture of phenyl-substituted and nonsubstituted pyrrolopyrazino annulated species as reaction products.File in questo prodotto:
| File | Dimensione | Formato | |
|---|---|---|---|
|
acs.orglett.6b01314.pdf
solo utenti autorizzati
Licenza:
Copyright dell'editore
Dimensione
721.47 kB
Formato
Adobe PDF
|
721.47 kB | Adobe PDF | Visualizza/Apri Richiedi una copia |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
