The tetraferrocenylporphyrin synthetic procedure was performed varying different reaction conditions. Mg, Mn, Pd and Cd complexes were synthesized and preliminarily studied. The results obtained show that the synthetic procedure strongly depends on catalyst, solvent and reagents concentration, even more than what observed with similar tetraarylporphyrins; concentration of substrates plays an important role in determining the outcome of the reactions.
Tiravia, M., Vecchi, A., Sabuzi, F., Pomarico, G., Coletti, A., Floris, B., et al. (2016). Synthesis of tetraferrocenylporphyrin and new metal complexes: searching for reliable synthetic procedures. JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 20(1), 421-428 [10.1142/S108842461650022X].
Synthesis of tetraferrocenylporphyrin and new metal complexes: searching for reliable synthetic procedures
Sabuzi, F;FLORIS, BARBARA;CONTE, VALERIA;GALLONI, PIERLUCA;
2016-04-01
Abstract
The tetraferrocenylporphyrin synthetic procedure was performed varying different reaction conditions. Mg, Mn, Pd and Cd complexes were synthesized and preliminarily studied. The results obtained show that the synthetic procedure strongly depends on catalyst, solvent and reagents concentration, even more than what observed with similar tetraarylporphyrins; concentration of substrates plays an important role in determining the outcome of the reactions.| File | Dimensione | Formato | |
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J. Porphyrins Phthalocyanines 2016 v20 421–428.pdf
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