A novel method for the preparation of corroles with beta-fused pyrazino rings was developed, exploiting a one-pot reaction of 2,3-diaminocorroles (or 2,3,17,18-tetraaminocorroles) with different diones; a variety of pi-extended corroles were obtained in moderate yields as copper complexes, which can then be de-metallated to give the corresponding free base in good yields.

Berna, B., NARDIS, S., MANDOJ, F., Fronczek, F., Smith, K., & PAOLESSE, R. (2016). Extending the corrole ring conjugation: preparation of beta,beta '-fused 2,3-[1 ',2 '-b]-pyrazinocorroles. ORGANIC & BIOMOLECULAR CHEMISTRY, 14(10), 2891-2897 [10.1039/c5ob02572a].

Extending the corrole ring conjugation: preparation of beta,beta '-fused 2,3-[1 ',2 '-b]-pyrazinocorroles

NARDIS, SARA
;
MANDOJ, FEDERICA;PAOLESSE, ROBERTO
2016

Abstract

A novel method for the preparation of corroles with beta-fused pyrazino rings was developed, exploiting a one-pot reaction of 2,3-diaminocorroles (or 2,3,17,18-tetraaminocorroles) with different diones; a variety of pi-extended corroles were obtained in moderate yields as copper complexes, which can then be de-metallated to give the corresponding free base in good yields.
Pubblicato
Rilevanza internazionale
Articolo
Esperti anonimi
Settore CHIM/07 - Fondamenti Chimici delle Tecnologie
English
Con Impact Factor ISI
Berna, B., NARDIS, S., MANDOJ, F., Fronczek, F., Smith, K., & PAOLESSE, R. (2016). Extending the corrole ring conjugation: preparation of beta,beta '-fused 2,3-[1 ',2 '-b]-pyrazinocorroles. ORGANIC & BIOMOLECULAR CHEMISTRY, 14(10), 2891-2897 [10.1039/c5ob02572a].
Berna, B; Nardis, S; Mandoj, F; Fronczek, F; Smith, K; Paolesse, R
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2108/149229
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