Novel complexes between methyltrioxorhenium (MTO) and bis(fluorous- ponytailed) 2,2′bipyridines (bpy-Fn) were synthesized and used for the oxidation of alkenes with hydrogen peroxide under fluorous catalysis. High conversions and yields of the corresponding epoxides were obtained.
Saladino, R., Ginnasi, M., Collalto, D., Bernini, R., Crestini, C. (2010). An Efficient and Selective Epoxidation of Olefins with Novel Methyltrioxorhenium/(Fluorous Ponytailed) 2,2′-Bipyridine Catalysts. ADVANCED SYNTHESIS & CATALYSIS, 352(8), 1284-1290 [10.1002/adsc.201000032].
An Efficient and Selective Epoxidation of Olefins with Novel Methyltrioxorhenium/(Fluorous Ponytailed) 2,2′-Bipyridine Catalysts
CRESTINI, CLAUDIA
2010-01-01
Abstract
Novel complexes between methyltrioxorhenium (MTO) and bis(fluorous- ponytailed) 2,2′bipyridines (bpy-Fn) were synthesized and used for the oxidation of alkenes with hydrogen peroxide under fluorous catalysis. High conversions and yields of the corresponding epoxides were obtained.File in questo prodotto:
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