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EnglishVanadyl N,N'-bis(salicylidene)-o-phenylenediamine (salophen) complexes have been extensively investigated by cyclic voltammetry, UV-visible spectroscopy and theoretical calculations in MeCN, THF (tetrahydrofuran) and DMF (N,N-dimethylformamide), in order to elucidate the overall factors that influence the electronic density of the metal and therefore the properties of these complexes in various applications. Different substituents were introduced into the salophen skeleton to change the vanadium electron density. Results obtained and here presented showed that the substituents influence the metal electronic character in a way that cannot be easily predicted by considering only the electronic effect. Similarly, the solvent polarity or coordination ability affects the metal complex properties in an unpredictable way. Therefore, experimental and theoretical data here collected are a powerful tool to a priori design salophen ligands to obtain vanadyl complexes having the specific electronic properties suitable for desired applications.
Bertini, S., Coletti, A., Floris, B., Conte, V., & Galloni, P. (2015). Investigation of VO-salophen complexes electronic structure. JOURNAL OF INORGANIC BIOCHEMISTRY, 147, 44-53.
| Tipologia: | Articolo su rivista |
| Citazione: | Bertini, S., Coletti, A., Floris, B., Conte, V., & Galloni, P. (2015). Investigation of VO-salophen complexes electronic structure. JOURNAL OF INORGANIC BIOCHEMISTRY, 147, 44-53. |
| URL: | http://www.sciencedirect.com/science/article/pii/S0162013415000677 |
| Altre informazioni significative: | Cost Actions CM1003 “Biological oxidation reactions—mechanisms and design of new catalysts” and CM1205 “Catalytic Routines for Small Molecule Activation (CARISMA)” PRIN 2010–2011 project 2010FM738 |
| Lingua: | English |
| Settore Scientifico Disciplinare: | Settore CHIM/06 - Chimica Organica |
| Revisione (peer review): | Esperti anonimi |
| Tipo: | Articolo |
| Rilevanza: | Rilevanza internazionale |
| Digital Object Identifier (DOI): | http://dx.doi.org/10.1016/j.jinorgbio.2015.03.003 |
| Stato di pubblicazione: | Pubblicato |
| Data di pubblicazione: | 2015 |
| Titolo: | Investigation of VO-salophen complexes electronic structure |
| Autori: | |
| Autori: | Bertini, S; Coletti, A; Floris, B; Conte, V; Galloni, P |
| Appare nelle tipologie: | 01 - Articolo su rivista |
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| File | Descrizione | Tipologia | Licenza | |
|---|---|---|---|---|
| j inorg biochem 2015 v147 p44.pdf | N/A | Copyright dell'editore | Open Access Visualizza/Apri |
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