We report on the optical properties of two dye molecules absorbing in the near infrared region (0.8-1.1μm) and emitting up to 1.3μm. The chromophores are embedded in hybrid organic/inorganic silicon-based films synthesized by a modified sol-gel technique. Femtosecond time-resolved emission spectra have been measured in order to determine the effect of the solid cage on the excited state dynamics of the trapped molecules. For comparison, measurements in different solvents are reported and an estimation of the relative quantum efficiency in solid glassy material with respect to liquid solutions is given. Measurements are discussed in terms of physical and chemical interactions with the host matrix. © 2001 Elsevier Science B.V. All rights reserved.

Prosposito, P., Casalboni, M., DE MATTEIS, F., Glasbeek, M., Quatela, A., Van Veldhoven, E., et al. (2001). Femtosecond dynamics of IR molecules in hybrid materials. JOURNAL OF LUMINESCENCE, 94-95, 641-644 [10.1016/S0022-2313(01)00353-2].

Femtosecond dynamics of IR molecules in hybrid materials

PROSPOSITO, PAOLO;CASALBONI, MAURO;DE MATTEIS, FABIO;QUATELA, ALESSIA;
2001

Abstract

We report on the optical properties of two dye molecules absorbing in the near infrared region (0.8-1.1μm) and emitting up to 1.3μm. The chromophores are embedded in hybrid organic/inorganic silicon-based films synthesized by a modified sol-gel technique. Femtosecond time-resolved emission spectra have been measured in order to determine the effect of the solid cage on the excited state dynamics of the trapped molecules. For comparison, measurements in different solvents are reported and an estimation of the relative quantum efficiency in solid glassy material with respect to liquid solutions is given. Measurements are discussed in terms of physical and chemical interactions with the host matrix. © 2001 Elsevier Science B.V. All rights reserved.
Pubblicato
Rilevanza internazionale
Articolo
Sì, ma tipo non specificato
Settore FIS/03 - Fisica della Materia
Settore FIS/01 - Fisica Sperimentale
Settore CHIM/02 - Chimica Fisica
Settore ING-IND/23 - Chimica Fisica Applicata
English
Fluorescence quantum efficiency; IR dyes; Sol-gel technique; Upconversion; Physical and Theoretical Chemistry; Atomic and Molecular Physics, and Optics
Prosposito, P., Casalboni, M., DE MATTEIS, F., Glasbeek, M., Quatela, A., Van Veldhoven, E., et al. (2001). Femtosecond dynamics of IR molecules in hybrid materials. JOURNAL OF LUMINESCENCE, 94-95, 641-644 [10.1016/S0022-2313(01)00353-2].
Prosposito, P; Casalboni, M; DE MATTEIS, F; Glasbeek, M; Quatela, A; Van Veldhoven, E; Zhang, H
Articolo su rivista
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2108/130118
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 18
  • ???jsp.display-item.citation.isi??? 19
social impact