The template effect of 1,5-Bis[2-(2-triisopropyloxyethoxy)ethoxy]naphthalene (5) on the ring closure reaction of 2-(4-Bromomethylbenzyl)-7-[4-(2,7-diazapyrenyl)methylbenzyl]-2,7-diazapyrenium (3), to give the corresponding [2]rotaxane (7), has been quantitatively evaluated. The results are compared to those relative to the self-assembly of [2]rotaxane (8), and [2]pseudorotaxanes (9) and (10).
Bruschini, M., Doddi, G., Ercolani, G., Mencarelli, P. (2010). Template Effect in the Self-Assembly of a [2]Rotaxane Containing Diazapyrenium Units. PROGRESS IN REACTION KINETICS AND MECHANISM, 35(2), 209-217 [10.3184/146867810X12699638527777].
Template Effect in the Self-Assembly of a [2]Rotaxane Containing Diazapyrenium Units
ERCOLANI, GIANFRANCO;
2010-05-01
Abstract
The template effect of 1,5-Bis[2-(2-triisopropyloxyethoxy)ethoxy]naphthalene (5) on the ring closure reaction of 2-(4-Bromomethylbenzyl)-7-[4-(2,7-diazapyrenyl)methylbenzyl]-2,7-diazapyrenium (3), to give the corresponding [2]rotaxane (7), has been quantitatively evaluated. The results are compared to those relative to the self-assembly of [2]rotaxane (8), and [2]pseudorotaxanes (9) and (10).File in questo prodotto:
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