The high sintering temperature of Yttrium doped barium zirconate (BZY), the most promising high temperature proton conductor (HTPC) for Intermediate Temperature (400e750 C) Solid Oxide Fuel Cells (IT-SOFCs), has been reduced by using ZnO as a sintering aid. Obtaining a dense electrolyte at a reduced temperature allows conventional fuel cell preparation methods. A reproducible spin coating method to fabricate highly performing anode supported button cells with dense micrometric BZYZn electrolyte layers has been developed. The electrochemical characterization of button cells at 600 C shows promising performance, higher than that of comparable fuel cells from literature
Luisetto, I., Licoccia, S., D'Epifanio, A., Sanson, A., Mercadelli, E., DI BARTOLOMEO, E. (2012). Electrochemical performance of spin coated dense BaZr0.80Y0.16Zn0.04O3-d membranes. JOURNAL OF POWER SOURCES, 220, 280-285 [10.1016/j.jpowsour.2012.07.136].
Electrochemical performance of spin coated dense BaZr0.80Y0.16Zn0.04O3-d membranes
LICOCCIA, SILVIA;D'EPIFANIO, ALESSANDRA;DI BARTOLOMEO, ELISABETTA
2012-01-01
Abstract
The high sintering temperature of Yttrium doped barium zirconate (BZY), the most promising high temperature proton conductor (HTPC) for Intermediate Temperature (400e750 C) Solid Oxide Fuel Cells (IT-SOFCs), has been reduced by using ZnO as a sintering aid. Obtaining a dense electrolyte at a reduced temperature allows conventional fuel cell preparation methods. A reproducible spin coating method to fabricate highly performing anode supported button cells with dense micrometric BZYZn electrolyte layers has been developed. The electrochemical characterization of button cells at 600 C shows promising performance, higher than that of comparable fuel cells from literatureFile | Dimensione | Formato | |
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