The isomorphic substitution applied to solutions of NH4PtCl4 and NH4PdCl4 allows to show the existence of 2 bound water molecules at the apical sites of PtCl42- and PdCl42- ions. The Pt(Pd)-H2O distance results equal to 2.77 Angstrom. (C) 1998 Elsevier Science B.V.

Caminiti, R., Carbone, M., Sadun, C. (1998). Palladium (II) and platinum (II) aqueous solutions. Evidence for the solvation of the [PdCl4](2-) and [PtCl4](2-) ions. JOURNAL OF MOLECULAR LIQUIDS, 75(2), 149-158 [10.1016/S0167-7322(98)82003-5].

Palladium (II) and platinum (II) aqueous solutions. Evidence for the solvation of the [PdCl4](2-) and [PtCl4](2-) ions

CARBONE, MARILENA;
1998-01-01

Abstract

The isomorphic substitution applied to solutions of NH4PtCl4 and NH4PdCl4 allows to show the existence of 2 bound water molecules at the apical sites of PtCl42- and PdCl42- ions. The Pt(Pd)-H2O distance results equal to 2.77 Angstrom. (C) 1998 Elsevier Science B.V.
1998
Pubblicato
Rilevanza internazionale
Articolo
Sì, ma tipo non specificato
Settore CHIM/03 - CHIMICA GENERALE E INORGANICA
Settore CHIM/02 - CHIMICA FISICA
English
Con Impact Factor ISI
X-RAY-DIFFRACTION; SQUARE-PLANAR SUBSTITUTIONS; PRESSURE NMR KINETICS; DIMETHYL-SULFOXIDE; WATER-EXCHANGE; VARIABLE-TEMPERATURE; AQUA COMPLEXES; CHLORO-AQUA; MECHANISM; TETRAAQUAPLATINUM(II)
Caminiti, R., Carbone, M., Sadun, C. (1998). Palladium (II) and platinum (II) aqueous solutions. Evidence for the solvation of the [PdCl4](2-) and [PtCl4](2-) ions. JOURNAL OF MOLECULAR LIQUIDS, 75(2), 149-158 [10.1016/S0167-7322(98)82003-5].
Caminiti, R; Carbone, M; Sadun, C
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2108/42747
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