In this account, the author describes the synthetic efforts of his group on the preparation and functionalization of corrole derivatives. The work started with beta-alkylcorroles and continued with the preparation of 5,10,15-triarylcorroles. The peripheral functionalization of both the beta-alkyl- and meso-triarylcorroles is described, together with several examples of the intriguing and unexpected reactivity of this deceptive macrocycle in these reactions.

Paolesse, R. (2008). Corrole: The little big porphyrinoid. SYNLETT(15), 2215-2230 [10.1055/s-2008-1078687].

Corrole: The little big porphyrinoid

PAOLESSE, ROBERTO
2008-01-01

Abstract

In this account, the author describes the synthetic efforts of his group on the preparation and functionalization of corrole derivatives. The work started with beta-alkylcorroles and continued with the preparation of 5,10,15-triarylcorroles. The peripheral functionalization of both the beta-alkyl- and meso-triarylcorroles is described, together with several examples of the intriguing and unexpected reactivity of this deceptive macrocycle in these reactions.
2008
Pubblicato
Rilevanza internazionale
Articolo
Esperti anonimi
Settore CHIM/07 - FONDAMENTI CHIMICI DELLE TECNOLOGIE
English
Con Impact Factor ISI
Complexes; Corroles; Functionalization; Porphyrinoids; Tetrapyrroles
Paolesse, R. (2008). Corrole: The little big porphyrinoid. SYNLETT(15), 2215-2230 [10.1055/s-2008-1078687].
Paolesse, R
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2108/27680
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