A diiminoisoindolo-pyrazino unit was annulated to the β-pyrrolic position of the Zn complex of tetraphenylporphyrin, giving a macrocycle with an expanded π system in satisfactory yields. The crystal structure of this derivative evidenced the formation of a hydrogen bond network. The interaction of the β-fused isoindoline porphyrin derivative with nucleotides and nucleic acids has been investigated. © 2016 The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.
Mandoj, F., D'Urso, A., Nardis, S., Monti, D., Stefanelli, M., Gangemi, C., et al. (2016). The interaction of a β-fused isoindoline-porphyrin conjugate with nucleic acids. NEW JOURNAL OF CHEMISTRY, 40(7), 5662-5665 [10.1039/c5nj03201f].
The interaction of a β-fused isoindoline-porphyrin conjugate with nucleic acids
MANDOJ, FEDERICA;NARDIS, SARA;MONTI, DONATO;STEFANELLI, MANUELA
;PAOLESSE, ROBERTO
2016-01-01
Abstract
A diiminoisoindolo-pyrazino unit was annulated to the β-pyrrolic position of the Zn complex of tetraphenylporphyrin, giving a macrocycle with an expanded π system in satisfactory yields. The crystal structure of this derivative evidenced the formation of a hydrogen bond network. The interaction of the β-fused isoindoline porphyrin derivative with nucleotides and nucleic acids has been investigated. © 2016 The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.File | Dimensione | Formato | |
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