The interaction between small unsaturated hydrocarbon molecules of C(2)H(4) with a vicinal silicon (001) surface is studied by means of reflectance anisotropy spectroscopy and analyzed with first principles calculations. Our results confirm that ethylene adsorbs without breaking the silicon dimers. Comparison of theoretical optical spectra with experimental data shows that the C(2)H(4) molecules lay on top of the silicon dimers from low to high coverage. This occurs even though, from a purely energetic point of view, a bridge configuration would be favorable at 1 monolayer coverage.

Marsili, M., Witkowski, N., Pulci, O., Pluchery, O., Silvestrelli, P., DEL SOLE, R., et al. (2008). Adsorption of small hydrocarbon molecules on Si surfaces: Ethylene on Si(001). PHYSICAL REVIEW. B, CONDENSED MATTER AND MATERIALS PHYSICS, 77(12) [10.1103/PhysRevB.77.125337].

Adsorption of small hydrocarbon molecules on Si surfaces: Ethylene on Si(001)

MARSILI, MARGHERITA;PULCI, OLIVIA;DEL SOLE, RODOLFO;
2008-01-01

Abstract

The interaction between small unsaturated hydrocarbon molecules of C(2)H(4) with a vicinal silicon (001) surface is studied by means of reflectance anisotropy spectroscopy and analyzed with first principles calculations. Our results confirm that ethylene adsorbs without breaking the silicon dimers. Comparison of theoretical optical spectra with experimental data shows that the C(2)H(4) molecules lay on top of the silicon dimers from low to high coverage. This occurs even though, from a purely energetic point of view, a bridge configuration would be favorable at 1 monolayer coverage.
2008
Pubblicato
Rilevanza internazionale
Articolo
Esperti anonimi
Settore FIS/03 - FISICA DELLA MATERIA
English
Marsili, M., Witkowski, N., Pulci, O., Pluchery, O., Silvestrelli, P., DEL SOLE, R., et al. (2008). Adsorption of small hydrocarbon molecules on Si surfaces: Ethylene on Si(001). PHYSICAL REVIEW. B, CONDENSED MATTER AND MATERIALS PHYSICS, 77(12) [10.1103/PhysRevB.77.125337].
Marsili, M; Witkowski, N; Pulci, O; Pluchery, O; Silvestrelli, P; DEL SOLE, R; Borensztein, Y
Articolo su rivista
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2108/114753
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 31
  • ???jsp.display-item.citation.isi??? 29
social impact